Aurosilane
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| Names | |
|---|---|
| IUPAC name
Tetraaurosilane
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| Other names
Silicon tetraauride
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| Identifiers | |
3D model (JSmol)
|
|
| |
| |
| Properties | |
| SiAu4 | |
| Molar mass | 675.159 |
| Related compounds | |
Other anions
|
silane |
Other cations
|
caesium auride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Aurosilane is an inorganic compound with a chemical formula of SiAu4. In this compound, gold acts as an electron acceptor with a valence of -1. Aurosilane has been isolated as a type of gold silane.[1] Its unit cell parameters are a=5.658, c=5.605 A.[2] The LUMO and the four Si-Au bonding orbitals of SiAu4 are similar to those of SiH4.[3]
In addition, silicon can also form other compounds with gold such as Si3Au3[4]
References
- ^ Kiran, Boggavarapu; Li, Xi; Zhai, Hua-Jin; Cui, Li-Feng; Wang, Lai-Sheng (2004-04-13). "[SiAu4]: Aurosilane". Angewandte Chemie International Edition. 43 (16): 2125–2129. doi:10.1002/anie.200353602. ISSN 1433-7851. PMID 15083462.
- ^ Tasci, Emre S.; Sluiter, Marcel H.F.; Pasturel, Alain; Villars, Pierre (January 2010). "Liquid structure as a guide for phase stability in the solid state: Discovery of a stable compound in the Au–Si alloy system". Acta Materialia. 58 (2): 449–456. Bibcode:2010AcMat..58..449T. doi:10.1016/j.actamat.2009.09.023. Archived from the original on 2020-02-12. Retrieved 2019-11-19.
- ^ Atomic Clusters: From Gas Phase to Deposited. Elsevier. 2007-05-24. ISBN 978-0-08-047595-0.
- ^ Kiran, Boggavarapu; Li, Xi; Zhai, Hua-Jin; Wang, Lai-Sheng (2006). "Gold as hydrogen: Structural and electronic properties and chemical bonding in Si3Au3+/0/-and comparisons to Si3H3+/0/-" (PDF). The Journal of Chemical Physics. 125 (125): 133204. Bibcode:2006JChPh.125m3204K. doi:10.1063/1.2216707. PMID 17029451. Archived from the original (PDF) on 2015-12-25. Retrieved 2023-05-20.
External reading
- Pyykkö, Pekka (October 2002). "Relativity, Gold, Closed‐Shell Interactions, and CsAu⋅NH3". Angewandte Chemie International Edition. 41 (19): 3573–3578. doi:10.1002/1521-3773(20021004)41:19<3573::AID-ANIE3573>3.0.CO;2-R. PMID 12370896.
- Wang, Lai-Sheng (2010). "Covalent gold" (PDF). Physical Chemistry Chemical Physics. 12 (31): 8694–8705. Bibcode:2010PCCP...12.8694W. doi:10.1039/c003886e. PMID 20567749. Archived from the original (PDF) on 2016-03-04. Retrieved 2023-05-20.
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